Effect of the sintering additive content on the protective passive oxidation behaviour of pressureless liquid-phase-sintered SiC

The long-term oxidation behaviour in air of pressureless liquid-phase-sintered SiC was investigated as a function of the sintering-additive content (a mixture of Y₂O₃ and Al₂O₃ in the 3:5 molar ratio) at oxidizing temperatures in the interval 1100–1300 °C. It is shown that oxidation under these mild conditions is always passive, and with formation of protective oxide scales. However, the oxidation kinetics cannot be described appropriately by the parabolic-rate law. Instead, due to the gradual crystallization of the oxide scales during oxidation, it is more complex, exhibiting two different stretches given respectively by the arctan- and parabolic-rate laws. Furthermore, it was found that the rate-limiting mechanism of the initial arctan oxidation is the outward diffusion of metal cations from the secondary intergranular phase into the oxide scale, with the activation energy of the oxidation being very high and decreasing from 545 to 432 kJ/mol with increasing sintering-additive content from 5 to 20 wt%. The rate-limiting mechanism of the subsequent parabolic oxidation is however the inward diffusion of oxygen through the multicomponent oxide scale, with the activation energy being lower than before and also decreasing from 345 to 205 kJ/mol as the sintering-additive content increases from 5 to 20 wt%. It is also shown that the oxidation resistance decreases with increasing sintering-additive content, but that while the decrease is moderate up to 10 wt%, it is very marked for greater contents.     

Studies of the pulse charge of lead-acid batteries for photovoltaic applications: Part IV. Pulse charge of the negative plate

The paper discusses the influence of the state of charge and pulse charge frequency on the mechanism of the lead-acid battery recharge with pulse current. The data from the pulse charge transients of the negative plate potential at various frequencies show that a decrease of the pulse charge frequency keeping constant average pulse current can impede the charge reaction leading to earlier start of the hydrogen evolution reaction. The dependence of the electrochemical double layer (EDL) capacitance on the state of charge was estimated both during the charge and the discharge using electrochemical impedance spectroscopy measurements at open circuit, followed by equivalent circuit modelling. These data were used to derive the dependence of the average double layer current on SOC and pulse charge frequency. The results show that in the end of the charge almost all of the charge proceeds with the participation of EDL in a certain pulse frequency domain. Using the data from the impedance measurements the optimal pulse charge frequencies were predicted, considering the existence of “electrochemical resonance”. The latter appears when the pulse charge frequency approaches the characteristic frequency of the Pb electrodeposition process, given by the product between EDL capacitance and the charge transfer resistance.     

Effect of various coal gas contaminants on the performance of solid oxide fuel cells: Part III. Synergistic effects

The coal-derived gas from a coal gasifier contains multiple contaminants, and their synergistic effects may not be simply the additive influences of individual contaminants. The present work presents the results of a study of the synergistic effects of four contaminants of major concern—S, As, P, and Cl, at the ppm level and in combinations of two, three, or four kinds—on the performance of Ni-YSZ/YSZ/LSM solid oxide fuel cells. The results indicate that both cell performance and morphology differ significantly in cells exposed to a single contaminant, and that cell performance is not simply the additive influence of each contaminant. Synergistic effects can be very destructive (accelerated degradation or even cell failure) when S is in the presence with As/P, but can also be beneficial (stabilization in power density variations over time or a slowed degradation rate) when Cl is present with other contaminants. Cl can even partially restore performance loss when it is introduced after P is already present. Therefore, with the addition of Cl the tolerance limit of SOFCs for the other three contaminants can be greatly increased. We speculate that the affinity of the contaminants to Ni catalyst increases in the following order: As < P < Cl. The interactions between and among these contaminants and possible mechanisms for their destructive and beneficial synergistic effects are discussed.     

Standardization for an innovative world

Standardization is beneficial for society in general and for research and innovation in particular. Standardization bodies as well as policymakers should promote the use of standards as a way of disseminating knowledge, exploiting research results and reducing time to market for the “innovation”.Several examples are presented here with regard to the standardization of research/innovation in the cement field. From cement manufacturing to nanotechnology applied to additives, cement and special concretes, it is possible to find good examples of innovation/research activities linked to standardization.     

New cements for the 21st century: The pursuit of an alternative to Portland cement

Preparation of this article entailed authors analyzing the contents of quite a number of papers, although the main objective was never to review the state of the art of new cements. Rather authors intend to discuss why they believe alkaline activated cement can be positioned at the epicentre of a new and necessary transition from today's Portland cement to the new cements of the future. A brief history of alkaline cements serves as an introduction to the technology itself. The interest roused around calcium sulfoaluminate-based cements is also reviewed, albeit summarily. The greater part of the article focuses, however, on alkaline cements which are classified into five categories. The fundamental chemical and structural characteristics of aluminosilicate-based alkaline cements are also described, and the key advances made in the understanding of synthetic gels are discussed. The paper ultimately finds hybrid cements to be technologically viable materials for contemporary construction.     

The SR-GCWS hybrid algorithm for solving the capacitated vehicle routing problem

The capacitated vehicle routing problem (CVRP) is a well known problem which has long been tackled by researchers for several decades now, not only because of its potential applications but also due to the fact that CVRP can be used to test the efficiency of new algorithms and optimization methods. The objective of our work is to present SR-GCWS, a hybrid algorithm that combines a CVRP classical heuristic with Monte Carlo simulation using state-of-the-art random number generators. The resulting algorithm is tested against some well-known benchmarks. In most cases, our approach is able to compete or even outperform much more complex algorithms, which is especially interesting if we consider that our algorithm does not require any previous parameter fine-tuning or set-up process. Moreover, our algorithm has been able to produce high-quality solutions almost in real-time for most tested instances. Another important feature of the algorithm worth mentioning is that it uses a randomized constructive heuristic, capable of generating hundreds or even thousands of alternative solutions with different properties. These alternative solutions, in turn, can be really useful for decision-makers in order to satisfy their utility functions, which are usually unknown by the modeler. The presented methodology may be a fine framework for the development of similar algorithms for other complex combinatorial problems in the routing arena as well as in some other research fields.     

New Anacardic Acid‐Inspired Benzamides: Histone Lysine Acetyltransferase Activators

A series of N‐(4‐cyano‐3‐trifluoromethyl‐phenyl)‐2‐ethoxy‐6‐alkyl (and alkenyl) benzamides related to the anacardic acid derivative CTPB have been prepared from 2,6‐dihydroxybenzoic acid with a Suzuki coupling and addition of the anion of 4‐cyano‐3‐trifluoromethylphenylamine to a benzodioxinone as the key steps. In U937 cells, these analogues, in particular 7 c , 7 d , 7 f and 7 j , induced cell‐cycle arrest in the G1 phase, caused apoptosis in about 20 % of the cells, and increased the acetylation levels of H3. These activities correlate with the enzymatic activation of histone lysine acetyltransferases (KATs): CBP and PCAF.     

Combining probabilistic algorithms, Constraint Programming and Lagrangian Relaxation to solve the Vehicle Routing Problem

This paper presents an original hybrid approach to solve the Capacitated Vehicle Routing Problem (CVRP). The approach combines a Probabilistic Algorithm with Constraint Programming (CP) and Lagrangian Relaxation (LR). After introducing the CVRP and reviewing the existing literature on the topic, the paper proposes an approach based on a probabilistic Variable Neighbourhood Search (VNS) algorithm. Given a CVRP instance, this algorithm uses a randomized version of the classical Clarke and Wright Savings constructive heuristic to generate a starting solution. This starting solution is then improved through a local search process which combines: (a) LR to optimise each individual route, and (b) CP to quickly verify the feasibility of new proposed solutions. The efficiency of our approach is analysed after testing some well-known CVRP benchmarks. Benefits of our hybrid approach over already existing approaches are also discussed. In particular, the potential flexibility of our methodology is highlighted.     

Recycled concrete made with different natural coarse aggregates exposed to high temperature

The recycled aggregates obtained from crushed waste concretes have different characteristics from those of natural aggregates. For that reason, the mixture proportions and the fresh and hardened properties of recycled concretes are different. The performance of recycled concrete exposed to high temperatures is not a very well-known subject since most studies have been conducted on conventional concretes. Recycled concretes with water/cement (w/c) ratios of 0.40 and 0.70, and made with three different types of natural coarse aggregate were exposed to 500 °C for 1 h. These concretes were evaluated by the ultrasonic method, resonance frequency, static modulus of elasticity and compressive strength, before and after heating, and compared with those obtained on similar conventional concretes containing the same type of natural coarse aggregate. The conventional and recycled concretes made with quartzitic coarse aggregate performed better after the heat treatment.     

Inhibitory pheromonal activity promoted by sulfur analogs of the sex pheromone of the female processionary mothThaumetopoea pityocampa (Denis and schiff)

New sulfur analogs of the sex pheromone of the female processionary mothThaumetopoea pityocampa have been found to be effective inhibitors of the natural pheromone activity both in EAG bioassays and field tests. The structures of these analogs have been derived from replacement of the oxygen atom(s) of the acetate group by sulfur (compounds 3-5) and the olefinic moiety of the enyne function by the isosteric SCH₂ group (compounds 6 and 7). The synthesis and biological activity of 3-[(Z)-12-pentadecen-10-ynylthio]-1,1,1-trifluoropropan-2-one (8), a closely related structure to the pheromone is also described.